The question is:
Show that if $S$ is a set of natural numbers such that no number in S can be expressed as a sum of other (not necessarily distinct) numbers in S, then $\sum_{ s \in S} \frac{1}{s} \leq 1$
So, $S \neq \{1,2\}$ since $2 = 1 + 1$; the same element can be used multiple times in the sum.
I looked online and found a Wikipedia page about sum-free sequences, but it seems those only deal with distinct subset sums of $S$. The bound for those is at best $2.85\dotsc$, so I was wondering if this more restrictive version of the problem was in the literature.
Claim: Given such a set $S$ that satisfies the conditions, if $a$ is the smallest term, then we have the stronger statement that
$$\sum \frac{1}{s} \leq \frac{1}{a} + \frac{1}{a+1} + \ldots + \frac{1}{2a-1} .$$
Equality occurs iff $ S = \{ a, a+1, a+2, \ldots 2a-1 \}$, which clearly satisfies the conditions.
Furthermore, equality holds in OP's case iff $ S = \{1\}$.
Proof of claim: I encourage you to do this yourself.
Hints: