I am trying to find a simplified form for this summation:
$$B(k,j) \equiv \sum_{i=1}^k (-1)^{k+i} {i \choose j} (k-1)_{i-1} \quad \quad \quad \text{for } 1 \leqslant j \leqslant k,$$
where the terms $(k-1)_{i-1} = (k-1) \cdots (k-i+1)$ are falling factorials (and $(k-1)_0 = 1$ by convention). I have done some work on this by generating a matrix of values of this quantity (see below) and I can recognise simplified forms for some of the parts of the matrix, but I have been unable to see a simplified form for the whole thing.
Computing the terms and looking for a pattern: In case it helps to try to recognise a pattern, I have computed a matrix of terms using the R code below. From the matrix of values it is clear that $B(k,k) = (k-1)!$ and $B(k,k-1) = (k-1) (k-1)!$. I also recognise that $B(k,1)$ is A000255. I do not recognise the overall matrix of numbers as any simple form.
#Generate function
B <- function(k,j) { T1 <- (-1)^(k+1:k);
T2 <- choose(1:k, j);
TT <- c(1,(k-1):1);
T3 <- cumprod(TT);
sum(T1*T2*T3); }
#Create matrix of terms
M <- 10;
BBB <- matrix(0, nrow = M, ncol = M);
for (k in 1:M) {
for (j in 1:k) { BBB[k,j] <- B(k,j); }}
BBB; #k is the row, j is the column
[,1] [,2] [,3] [,4] [,5] [,6] [,7] [,8] [,9] [,10]
[1,] 1 0 0 0 0 0 0 0 0 0
[2,] 1 1 0 0 0 0 0 0 0 0
[3,] 3 4 2 0 0 0 0 0 0 0
[4,] 11 21 18 6 0 0 0 0 0 0
[5,] 53 128 156 96 24 0 0 0 0 0
[6,] 309 905 1420 1260 600 120 0 0 0 0
[7,] 2119 7284 13950 16080 11160 4320 720 0 0 0
[8,] 16687 65821 148638 210210 190680 108360 35280 5040 0 0
[9,] 148329 660064 1715672 2870784 3207120 2392320 1149120 322560 40320 0
[10,] 1468457 7275537 21381624 41278104 54701136 50394960 31872960 13245120 3265920 362880
Some Asymptotic Approximations
The AM-GM inequality says $$ \frac{k!}{(k-i)!}\le\left(k-\frac{i-1}{2}\right)^i\tag1 $$ The fact that $$ \frac{k(k-i+1)}{\left(k-\frac{i-1}2\right)^2}=1-\left(\frac{\frac{i-1}2}{k-\frac{i-1}2}\right)^2\tag2 $$ allows us to derive $$ \frac{k!}{(k-i)!}\ge\left[1-\frac{\frac13\left(\frac{i+1}2\right)^3}{\left(k-\frac{i-1}2\right)^2}\right]\left(k-\frac{i-1}{2}\right)^i\tag3 $$ and therefore, $$ \frac{k!}{(k-i)!}\sim\left(k-\frac{i-1}{2}\right)^i\tag4 $$ from which, we get $$ \begin{align} \frac{\binom{k-j}{i}}{\binom{k}{i}} &\sim\left(\frac{k-j-\frac{i-1}2}{k-\frac{i-1}2}\right)^i\\ &\sim\left(\frac{k-j}{k}\right)^i\left(1-\frac{i(i-1)j}{2k(k-j)}\right)\\[6pt] &=\left(\frac{k-j}{k}\right)^i-i(i-1)\left(\frac{k-j}{k}\right)^{i-2}\frac{j(k-j)}{2k^3}\tag5 \end{align} $$ and therefore, $$ \begin{align} \sum_{i=0}^\infty\frac{(-1)^i}{i!}\frac{\binom{k-j}{i}}{\binom{k}{i}} &\sim\sum_{i=0}^\infty\frac{(-1)^i}{i!}\left[\left(\frac{k-j}{k}\right)^i-i(i-1)\left(\frac{k-j}{k}\right)^{i-2}\frac{j(k-j)}{2k^3}\right]\\ &=e^{-\frac{k-j}k}\left(1-\frac{j(k-j)}{2k^3}\right)\\[3pt] &\sim e^{-\frac{k-j}k-\frac{j(k-j)}{2k^3}}\tag6 \end{align} $$
Approximation of the Sum
We don't get an exact closed form, but here is a pretty good asymptotic approximation: $$ \begin{align} \sum_{i=1}^k(-1)^{k+i}\binom{i}{j}(k-1)_{i-1} &=\frac1k\sum_{i=1}^k(-1)^{k-i}\binom{i}{j}(k)_i\\ &=\frac1k\sum_{i=0}^{k-1}(-1)^i\binom{k-i}{j}(k)_{k-i}\\ &=(k-1)!\binom{k}{j}\sum_{i=0}^{k-1}\frac{(-1)^i}{i!}\frac{\binom{k-j}{i}}{\binom{k}{i}}\\ &\sim\bbox[5px,border:2px solid #C0A000]{(k-1)!\binom{k}{j}e^{-\frac{k-j}k-\frac{j(k-j)}{2k^3}}}\tag7 \end{align} $$ This is good when $k$ is large, exact when $j=k$, and extremely close when $j=0$. In fact, it looks as if the ratio of the approximation to the actual sum is asymptotically $1+\frac{(4j+k)j(k-j)}{6k^5}$. The maximum of this ratio is when $\frac jk=\frac{3+\sqrt{21}}{12}\approx0.63188$, where $\frac{(4j+k)j(k-j)}{6k^5}=\frac{27+7\sqrt{21}}{432k^2}\approx\frac{0.13675}{k^2}$ .
For example, when $k=10$ and $j=5$, $(7)$ gives $54775664.104$, which is about $0.136\%$ above the value in the table in the question.