The formula for surface integral is given by:
$$\iint_S \overrightarrow F \cdot \hat n \space dS $$
I want to know about the $dS$ part.
For example: If the plane lies in the first octant then it is:
$$dS = \frac{dx \space dy}{|\hat k \cdot \hat n|}$$
There are also other case such as:
$$dS = \frac{dz \space dy}{|\hat i \cdot \hat n|}$$
and $$dS = \frac{dx \space dz}{|\hat j \cdot \hat n|}$$
How do I exactly decide which $dS$ formula to choose i.e. if the plane lies in fourth or second octant. How will I choose?
The plane (which appears only in a comment of yours) is of course infinite. I guess you are told to integrate over the triangle $S$ cut out of this plane by the first octant. This triangle projects down to the $(x,y)$-plane to the triangle $$S':=\left\{(x,y)\>\biggm|\>0\leq x\leq 6, \ \>0\leq y\leq4-{2\over3}x\right\}\ .$$ Now use the parametrization $$\phi:\quad S'\to S,\qquad (x,y)\mapsto \left(x,y,\ 2-{1\over3}x-{1\over2}y\right)$$ to compute the requested flow.
In order to proceed further we need the exact description of the (supposedly nonconstant) vector field $\vec F$ and the intended orientation of $S$.