I'm afraid this is one of those "amateur mathematician with no journal access" questions. Anyhow, Wikipedia (here) and OEIS give this closed form for the terms Sylvester's sequence:
$S_n = \lfloor E^{2^{n+1}} + \frac12\rfloor$ (where $E \approx 1.264$).
Is this the best we can do for a closed form, or is there an exact formula known? Is it known that there is no such formula?
To quote that Wikipedia article (emphasis mine):