Given P and Q are two statement and $\neg P$ is the negation of P, I want to show that
$\neg(P → Q) \implies (P\cap \neg Q)$
I can show the other way,
$(P\cap \neg Q)\implies \neg(P → Q)$
by assuming the condition and negation of the conclusion. Yet I do not know how to prove this equivalence from conditional statement to and statement since assuming the condition $\neg(P → Q)$ does not give any truth value for $P$ or $Q$.

Use indirect proofs. Reduction to Absurdity and Proof of Negation.
Assume $\neg P$ to derive $P\to Q$; a contradiction! Therefore deduce $P$.
Assume $Q$ to derive $P\to Q$; a contradiction! Therefore deducing $\neg Q$.