The eigenvalues of $\begin{pmatrix}0&A\\A^*&0\\ \end{pmatrix}$ are the singular values of $A$ along with the negative signs.
Here $A$ is an $n \times n$ matrix, has $n$ singular values. Here we are consider both $\lambda $ and $- \lambda$ if $\lambda$ is an singular value of $A$. Thus we have a set of $2n$ elements and we have to show that these are the eigenvalues of $\begin{pmatrix}0&A\\A^*&0\\ \end{pmatrix}$.
Need some hint to proceed with the problem.
A nice summary of the SVD:
$$Av_i=\sigma_i u_i \\ A^* u_i=\sigma_i v_i.$$
So build a single vector $x_i$ so that when you multiply out $Bx_i$, $A$ hits $v_i$ and $A^*$ hits $u_i$. Since the structure of $B$ already makes the two trade places, this will wind up giving you an eigenvector with eigenvalue $\sigma_i$. Now how do you get one with eigenvalue $-\sigma_i$?