Please see the graphs below.
From here we can see clearly that $x^{100}$ grows faster than $e^x$.
I zoomed out and checked up to $y=5000$ and the result is the same.
But I know that the growth of an exponential function is mathematically proven to be faster than any polynomial function.
Why? What does that phrase actually mean?


Take $x=1000$ which gives $$x^{100}=1.00 \times10^{300} \qquad \text{and} \qquad e^{x}=1.97 \times 10^{434}$$
In fact $e^x > x^{100}$ if $x > 648$.
Redo your plot on a log scale.
Edit
In fact, we can show that, for any real $a$, $e^x > x^a$ as soon as $$x > x_*= -a\, W_{-1}\left(-\frac{1}{a}\right)$$ where appears the second branch of Lambert function.
As a shortcut, $x_* \sim 1.05 \,a \log (a \log (a))$