The introduction rule for implication says that you can prove a statement of the form $P \implies Q$ by assuming $P$ and deducing $Q$. (Btw. I don't know why it's called an introduction rule - you don't introduce the implication, you eliminate it.)
My question is: can the introduction rule for implication be proven? If yes, how?
Named "introduction rule for implication", it's just what it says, it's the syntactical rule for which we introduce the symbol $\implies$ to signify that actually assuming $P$ one can deduce $Q$.
If you instead name it "deduction theorem" (DT, it's actually a metatheorem) you can follow the proof in wikipedia, on how to convert a proof using DT to a proof that doesn't use DT, provided your logic system has other axioms, of course). Thus, you see that DT is no necessary for the whole deduction process, so it is a theorem, and not an axiom.