By Baker–Campbell–Hausdorff formula, if $[v,w]=0$ for $v,w$ in the Lie algebra $\mathfrak g$ of a Lie group $G$ then $\exp(v)$ and $\exp(w)$ commute in $G$.
Does anyone know a reference or a method of proof of the following partial inverse: For $v,w$ sufficiently close to $0$ in $\mathfrak g$, $\exp(v)\exp(w)=\exp(w)\exp(v)$ implies $[v,w]=0$?
Being sufficiently close to zero is of course necessary here.
There is something similar: For connected Lie group G,
$$X, Y \in \mathfrak g \text{ commute if and only if } \exp(tX) \exp(sY) = \exp(sY) \exp(tX) \text{ for all $s,t \in \mathbb R$.} $$
I do not know direct proof of the converse, but it follow directly from a theorem in smooth manifold theory, which says that smooth vector fields commute iff their flows commute. You can read about it in Lee's Introduction to smooth manifolds.