I'm interested in knowing what is the meaning of the various equality symbols: $=,\sim, \cong,\approx,\equiv$.
For example, the speed of a car $V$ in m/s: what would be the meaning of each of these statements? $$V = 30\\ V\sim 30\\ V \cong 30\\ V \approx 30\\ V \equiv 30$$
If your example is about speed, then this a question for physicists and not for logicians.
The most important thing is that these symbols are precisely that - symbols. They can be defined to mean whatever you want them to. Of course, we try to keep some common basis of definitions across a particular topic. But even the standard equal sign can be used for different things: I could equate terms (like $2+2=4$), sets, whatever.
Now, back to speed, and the different "equality" symbols:
My point is, you need to be aware of what topic (or branch of mathematics) you're working on, as these symbols (and many others) will have their own interpretation.