Is it possible to construct $*$-isomorphism of (factor von Neumann) algebra $B(H)$ which is not unitary implementable?
The unitary implementation of $*$-isomorphism of $B(H)$
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Let $\theta:B(H)\to B(H)$ be a $*$-automorphism. Fix an orthonormal basis $\{\xi_j\}$ of $H$, and write $E_{jj}$ for the corresponding rank-one projections, i.e. $E_{jj}\xi=\langle\xi,\xi_j\rangle\,\xi_j$. We can expand $\{E_{jj}\}_j$ to a system of matrix units $\{E_{kj}\}_{k,j}$, where $E_{kj}\xi=\langle\xi,\xi_j\rangle\,\xi_k$.
Next notice that $\theta(E_{11})$ is also a rank-one projection (because $\theta$ being an automorphism forces it to be minimal). Let $\eta_1$ be a unit vector in the range of $\theta(E_{11})$.
Define $U:H\to H$, linear, by $U\xi_j=\theta (E_{j1})\eta_1$. Then $$\langle U\xi_j,U\xi_k\rangle=\langle \theta (E_{1k}E_{j1})\eta_1,\eta_1\rangle=\delta_{kj}=\langle\xi_j,\xi_k\rangle. $$So $U $ is a unitary and $\{\eta_j\}$, where $\eta_j=U\xi_j $, is an orthonormal basis (the observation that $\theta(E_{11})$ is minimal is necessary to guarantee that $U$ is onto).
Note that $\theta(E_{kj})$ is a rank-one operator sending $\eta_j\to\eta_k$ (because $\theta(E_{kj})\theta(E_{j1})=\theta(E_{kj}E_{j1})=\theta(E_{k1})$); this means that $\theta(E_{kj})\xi=\langle\xi,\eta_j\rangle\,\eta_k$. Then $$ UE_{kj}U^*\eta_t=UE_{kj}\xi_t=\delta_{j,t}U\xi_k=\delta_{j,t}\eta_k=\langle\eta_t,\eta_j\rangle\,\eta_k=\theta(E_{kj})\eta_t. $$
As finite linear combinations of the $E_{kj}$ are weakly dense and $\theta$ is normal (which implies weak-continuous on bounded sets), we get $\theta=U\cdot U^*$.
There's a classic trick to produce the unitary. I was told once who this is due to, but I've unfortunately forgotten. Recall that, if $\xi,\eta \in H$, then $\eta \otimes \overline \xi$ denotes the rank-1 operator which sends $\zeta \mapsto \langle \xi,\zeta \rangle \eta$. Here, the inner-product is conjugate linear in the 1st slot. It's easy to check that $T \cdot ( \eta \otimes \overline \xi) = (T \eta) \otimes \overline \xi$ and $(\eta \otimes \overline \xi ) \cdot T^* = \eta \otimes \overline{T \xi}$ whenever $T \in B(H)$.
Let $\theta$ be a $*$-automorphism of $B(H)$.
I left out the details, but they aren't too bad.