The function $f(k) = \mathbb{N}^k$ is a one to one function but it is not an onto function. Hence the function is not a one to one correspondence function.
Does that give sufficient justification to proof that the given set in not countable? Or is there any other way to approach the same.

$N^k$ is a set.
You are suppose to show whether a bijection between $\mathbb{N}$ and $\mathbb{N}^k$ exists.
Guide:
You might want to first verify whether the following is true.
If $A$ is countable and $B$ is countable, then their cartesian product $A \times B$ is countable and then you might want to consider using induction.