The question I am about to ask could have gone to the chat section but I want to have the answers/comments in an easy-to-refer-back-to style.
For (connected, pointed) topological spaces with trivial fundamental group, there is much already said in the literature and there is a term for such spaces: simply-connected spaces. If I want to search the literature for spaces with fundamental groups such as $\mathbb{Z}$, what terms are relevant?
Moreover, what is the story of spaces with prescribed fundamental groups other than the trivial group? I know this is a classical problem. Even in the simply connected case, there is not still a 'classification scheme' for simply connected smooth 4-manifolds. The Wikipedia page here gives one reason why many studies just consider the simply connected case as "the general case of many problems is already known to be intractable."
P.S. I have already found out about n-connected spaces.
The reason why spaces with trivial fundamental group (i.e. simply connected spaces) appear to be more studied than the others in the literature is principally due to the fact that every sufficiently nice space (here it says: connected, locally path connected and semi-locally simply connected) admits an universal cover, and many problems can be reduced to the study of simply connected spaces this way.