Let $A\in \mathbb{C}^{n\times n}$. If all eigenvalues of $A$ are real then $A\in \mathbb{R}^{n\times n}$
I would actually say this is not true because for example:
$$\det \begin{bmatrix}-i-\lambda&1\\\ 1&i-\lambda\\\end{bmatrix} = \lambda^2$$
Is this counterexample enough to say it's False?
This is correct. An easy way to construct lots of counterexamples is to take triangular matrices, with real elements on the diagonal, and non-real elements elsewhere.