Q. Let $f :\mathbb R → \mathbb R$ be a twice-differentiable function such that $f(\frac{1}{n})=0$ for every positive integer $n$. Then
$f(0)=0$
$f'(0)=0$
$f''(0)=0$
$f$ is a non zero polynomial
We can say 4 is not correct by taking $f(x)=x^4 \sin \frac{1}{x}$.
How to prove the rest of them?
For a function in $\mathcal C^2(\mathbf R)$, including at $0$, you can take the function $$f(x)=\begin{cases}x^5\sin\frac\pi x&\text{ if }x\ne 0,\\ 0&\text{ if }x=0. \end{cases}$$ (With a smaller integer exponent for $x$, it is not twice continuously differentiable at $0$.)