$\def\Hom{\operatorname{Hom}}$Suppose we are given functors $F:\mathcal{C}\rightarrow\mathcal{D}$ and $G,G':\mathcal{D}\rightarrow\mathcal{C}$ such that $G$ and $G'$ are both right adjoint to $F$. To show that $G$ and $G'$ are isomorphic, we wish to come up with a natural isomorphism between the two functors. This is how Awodey does it:
For any $D\in\mathcal{D}$ and any $C\in\mathcal{C}$, we have that $\Hom(C,GD)\cong \Hom(FC,D)\cong \Hom(C,G'D)$ simply using the hom-set definition of adjunctions. By the Yoneda principle, this means that $GD\cong G'D$ for all $D\in\mathcal{D}$.
Awodey then states that
But this isomorphism is natural in $D$, again by adjointness.
I dont' quite understand how the naturality follows from adjointness. Any help is appreciated.
The bijection $\hom(C,GD) \cong \hom(C,G'D)$ is natural in $C$, thus it is induced by an isomorphism $GD \cong G'D$ (Yoneda Lemma). But it is also natural in $D$, and since the Yoneda embedding is faithful, this means that $GD \cong G'D$ is natural in $D$. More details:
If $D \to E$ is a morphism, then
$\begin{array}{ccc} GD & \rightarrow & G'D \\ \downarrow & & \downarrow \\ GE & \rightarrow & G'E \end{array}$
commutes iff for every $C$ the diagram
$\begin{array}{ccc} \hom(C,GD) & \rightarrow & \hom(C,G'D) \\ \downarrow & & \downarrow \\ \hom(C,GE) & \rightarrow & \hom(C,G'E) \end{array}$
commutes.