From a textbook on Harmonic Analysis:
Question: Why does integration by parts yield
$$ T_{f'}(φ) = ∫_ℝ f'(x)φ(x)dx = - ∫_{ℝ}f(x)φ'(x)dx = -T_f(φ')? $$
Attempt. I know that Integration by Parts does yield that
$$ ∫_{ℝ}f(x)φ(x)dx = ∫_ℝ f'(x)φ(x)dx + ∫_{ℝ}f(x)φ'(x)dx $$
so that the equality would hold if $∫_{ℝ}f(x)φ(x)dx = 0$.

For a Schwartz function we have:
$\displaystyle \lim_{|x|\to \infty} f(x)φ(x)=0$
As a result, in other words, we have:
$\displaystyle f(x)φ(x)|_{-\infty}^{\infty}=0$
In integration by parts we have:
$\displaystyle ∫_ℝ f'(x)φ(x)dx + ∫_{ℝ}f(x)φ'(x)dx=f(x)φ(x)|_{-\infty}^{\infty} =0$
$\displaystyle \to ∫_ℝ f'(x)φ(x)dx=-∫_{ℝ}f(x)φ'(x)dx$