I have the following question:
$$x - 2y = 1$$ $$2x + 3y = 4$$
So let's say:
$$A = \left[ \begin{matrix} 1 & -2 \\ 2 & 3 \end{matrix} \right]$$
So according to some formula to $2 \times 2$ matrices:
$$A^{-1} = \frac{1}{7} \left [ \begin{matrix} 3 & 2 \\ -2 & 1 \end{matrix} \right ]$$
$$= \left [ \begin{matrix} \frac{3}{7} & \frac{2}{7} \\ \frac{-2}{7} & \frac{1}{7} \end{matrix} \right ]$$
So since
$$Ax = b$$
$$A^{-1} * Ax = A^{-1}b$$
$$x = A^{-1}b$$
So
$$A^{-1}b = \left [ \begin{matrix} \frac{3}{7} & \frac{2}{7} \\ \frac{-2}{7} & \frac{1}{7} \end{matrix} \right ] * \left [ \begin{matrix} 1 \\ 4 \end{matrix} \right ] = x = \left [ \begin{matrix} \frac{11}{7} \\ \frac{2}{7} \end{matrix} \right ] $$
so $x_1 = \frac{11}{7}$ and $y = \frac{2}{7}$
My question: When you solve for a column, is x the way to denote a whole column of variables? If B is a 2x1 matrix and $A^{-1}$ is a 2x2 matrix, does this mean that the x will assign two variables?
Also, does my solution look right?

Regarding your notation, you might like to define things explicitly to avoid misunderstanding.
We let x$=\begin{bmatrix} x\\ y\end{bmatrix}$, hence we know exactly what you are working with. You might like to choose another notation say $v=\begin{bmatrix} x\\ y\end{bmatrix}$ so that verbal communication becomes easier as well.
As to check the solution, it is clear that the determinant is non-zero, hence the solution is unique if exists. We just have to verify your solution.
$$\frac{11-2(2)}{7}=1$$ $$\frac{2(11)+3(2)}{7}=4$$
Your solution is correct.