Thinking about how you can put vector fields on homogeneous spaces that respect the homogeneity, I'm interested in the following situation:
Let $V$ be a nonzero vector field on a manifold $M$, let the simply connected group $G$ act transitively on $M$, and let $V$ be invariant under this action, so $g_* V=V$ for all $g\in G$.
Now an obvious way to construct such a vector field is if $G$ acts freely and transitively, since you can pick a vector at any point and push it forward to any other point under the group action. If the action is not free, the ambiguity in choice of group element means that this may not work; the stabilizer need not map $V$ to itself. It is easy to come up with examples where this is not an obstruction, but in all those I've been able to think of, the action can be restricted to a free and transitive one. Must this always be the case? In other words, is the following true?
Proposition: Then $G$ has a subgroup acting freely and transitively.
I think your question has a negative answer.
(We must exclude $n=2$ because the action of $SU(2)$ on $S^3$ is both transitive and free.)
To describe the action, we think of $S^{2n-1}\subseteq \mathbb{C}^n$ as $$S^{2n-1} = \{(z_1,...,z_n)\in\mathbb{C}^n: |z_1|^2 + \ldots + |z_n|^2 = 1\}.$$ For any $p\in S^{2n-1}$, we identify $T_p S^{2n-1}$ with the set of all vectors perpendicular to $p$.
Now, $SU(n)$ naturally acts on $\mathbb{C}^n$ just by multiplication and restricting the action to $S^{2n-1}$ gives the action we want.
Our vector field is the vector field tangent to the Hopf circles. More precisely, at the point $p\in S^{2n-1}$, $V(p) = ip$.
Then, because any element of $SU(n)$ is a complex linear map, we have $$A_\ast (V(p)) = A_\ast (ip) = A(ip) = i(Ap) = V(Ap)$$ (where we use the fact that the derivative of a linear map is itself in the second equality). Hence, $V(p)$ really is $SU(n)$ invariant.
Now, why doesn't any subgroup of $SU(n)$ acts freely and transitively on $S^{2n-1}$? One can copy the argument I used on your previous question: If a Lie group acts freely and transitively on a manifold, then the manifold is diffeomorphic to the Lie group, and in particular, carries a Lie group structure. But only $S^0$, $S^1$, and $S^3$ carry Lie group structures. (See, for example, an older answer of mine.