Brézis states that the functions in $W^{1,1}(I)$, with $I$ a bounded interval, are absolutely continuous, and that, for $u\in L^1(I)$, if the following holds for some constant $C$:
$$\left|\int_Iu\phi'\right|\leq C\|\phi\|_{L^\infty},$$
for all $\phi\in\mathcal{C}^1_c(I)$, then $u$ is of bounded variation. I cannot quite see why this holds. How can I prove these statements? And are these characterizations or only implications? For example, is $W^{1,1}(I)=AC(I)$ or is it just $W^{1,1}(I)\subseteq AC(I)$?
There is a difference in that the elements of $W^{1,1}$ are equivalence classes of functions (up to equality a.e.), while the elements of AC and BV may (or may not) be understood as actual functions, for which changing the value at a point matters. That said, there is a close relation:
$u\in W^{1,1}(I)$ if and only if $u$ has an absolutely continuous representative.
A proof may be found in most Sobolev spaces books under "absolute continuity on lines", for example section 10.3 in Sobolev Spaces by Leoni. Usually one proves the $n$-dimensional case, but the case $n=1$ is what I stated above.
Summary: A function is in $W^{1,1}(I)$ iff its distributional derivative is an $L^1$ function, and the antiderivatives of $L^1$ functions are precisely absolutely continuous functions.
With BV it's more complicated, because there are two competing definitions (in one dimension):
The first definition cares about pointwise values, the second does not (it operates with equivalence classes up to equality a.e.). The aforementioned book by Leoni uses notation BPV (bounded pointwise variation) for the former and BV for the latter. For example, $\chi_{\mathbb{Q}}$ is not in BPV, but is in BV (because it's the zero function as far as BV is concerned).
By the Riesz representation theorem, the property $\left|\int_Iu\phi'\right|\leq C\|\phi\|_{L^\infty}$ is equivalent to saying that the distribution $u'$ is a finite signed measure, and thus is equivalent to $u\in BV$.