A formula is valid if it is true for all values of its terms. Satisfiability refers to the existence of a combination of values to make the expression true. So in short, a proposition is satisfiable if there is at least one true result in its truth table, valid if all values it returns in the truth table are true.
Even given these definitions it is still not clear to me what sentences are valid or not.
What are some examples of sentences that are valid or (un)satisfiable?
If $A$ is a propositional variable, $ A\lor \lnot A$ is a valid sentence, since whatever value $A$ takes, this is true. Another is $A\to (B\to A).$ As you can check, whatever value $A$ and $B$ take, this is true.
A sentence that is satisfiable but not valid is the very simple sentence of just $$A,$$ which is true when $A$ is true and false if $A$ is false. Another is $A\land B.$ As you probably know, the truth table for $A\land B$ has both zeros and ones in it.
Finally, $ A\land \lnot A$ is unsatisfiable. You can see it's false regardless if $A$ is true or false. Another unsatisfiable sentence is $$ (A \lor B)\land \lnot A \land \lnot B,$$ which you can check is false for any truth values of $A$ and $B.$