What would the last digit be in a base 11 system? Base 12?
I'm mostly wondering because I was thinking of a base 36 system with digits 0-9 immediately followed by the letters A-Z but I wasn't sure if that would be considered a proper numeral system, or if there was something else in place.
The extra digits can be anything you want (the symbols 0-9 themselves are arbitrary, and could be switched around or replaced by other things, though that'd be adding unnecessary confusion). As Arturo mentions above, hexadecimal notation is common in computing, and there it is conventional to use $A=10$ through $F=15$.
If you want to stick to using the 10 Hindu-Arabic numerals and 26 English letters, and want to go past base 36, the Wikipedia article on positional notation describes how one might solve this by using groups of these symbols in each position.