Let $p$ be a prime number, let $\mathbb{Q}_p$ be the local field, by Hensel's lemma, we know it has $p-1$-th roots of unity, let $\zeta$ be a fixed primitive $p-1$-th root of unity in $\mathbb{Q}_p$.
Let $a,b\in\mathbb{Q}_p^*$, let $(a,b)_{\zeta}$ be the cyclic algebra defined by $\mathbb{Q}_p\langle x,y|x^{p-1}=a,y^{p-1}=b, xy=\zeta yx\rangle$.
Is there an explicit way to tell which class $[(a,b)_\zeta]\in\mathrm{Br}(\mathbb{Q}_p)=\mathbb{Q}/\mathbb{Z}$ is? (For example, when $a,b\in\mathbb{Q}$, how does the two rational numbers determine an element in $\mathbb{Q}/\mathbb{Z}$?)
I should clarify going into this that I don't know any class field theory, so I might say some silly things. The number you're trying to compute is the Hasse invariant of the cyclic algebra, and it should also correspond to a Hilbert symbol as in the comments. I found a nice formula for a special case of the Hilbert symbol in Section 3.3 of these notes (Lemma 3.22). Specialized to this case it gives
$$(a, b)_{\xi} = \omega \left( (-1)^{\nu(a) \nu(b)} \frac{b^{\nu(a)}}{a^{\nu(b)}} \bmod p \right)$$
where $\nu : \mathbb{Q}_p \to \mathbb{Z}$ is the valuation and $\omega : \mathbb{F}_p^{\times} \to \mu_{p-1}(\mathbb{Q}_p)$ is the Teichmüller character.
You asked in the comments about $p = 5, a = 2, b = 3$. In this case $\nu(a) = \nu(b) = 0$ so the Hilbert symbol is trivial. In order for it to be nontrivial at least one of $\nu(a)$ and $\nu(b)$ must be nonzero. For example, sticking to $p = 5$, if we take $a = 2, b = 5$ then we get
$$(1, 5)_{\xi} = \omega \left( \frac{1}{2} \bmod 5 \right) = \omega(3)$$
which is the unique $4^{th}$ root of unity in $\mathbb{Z}_5$ congruent to $3 \bmod 5$, and in particular primitive. Unfortunately I don't know exactly how this is identified with an element of $\mathbb{Q}/\mathbb{Z}$, although it must be either $\frac{1}{4}$ or $\frac{3}{4}$.