I has $Vs(t)$ as well as a wave form in picture. So what is a solution of $v(t)$ in the differential equation? I used Laplace transform for solving but it is incorrect. Next picture, it is a wave form of $v(t)$ when $Vm = 12V$, $T = 20ms$ but i must know the equation of v(t).
Thank you.


The first step is to figure out the Laplace transform of the voltage source.
In order to not confuse the voltage across the capacitor and the voltage source ($V_s$), lets call $V_s = E_s$.
$E_s$ is a periodic voltage source with period $T = 20~ ms = \dfrac{1}{50}$ seconds (or a circuit frequency of $50$ Hz (Hertz)). Because $E_s$ is a periodic source with interval $\left(0, \dfrac{1}{50}\right)$ seconds, it can be defined analytically as:
For a periodic function, $E_s$ with period $T \gt 0$, we have:
$$\mathscr{L}~(E_s(t)) = \dfrac{\int_0^T e^{-s t}E_s(t)~dt}{1-e^{-sT}} = \dfrac{\int_0^{1/50} e^{-s t}E_s(t)~dt}{1-e^{-s/50}}$$
However, we have:
$$\begin{align}\int_0^{1/50} e^{-s t}E_s(t)~dt & = \int_0^{1/100} e^{-s t}(12)~dt + \int_{1/100}^{1/50} e^{-s t}(0)~dt \\ \\ & = -\dfrac{12}{s}~(e^{-st})~\Bigr|_{t=0}^{t = 1/100} \\ \\ & = \dfrac{12}{s}(1 - e^{-s/100})\end{align}$$
So, we can simplify (note: $(1-e^{-s/50}) = (1-e^{-s/100})(1+e^{-s/100})$) and arrive at:
$$\mathscr{L}~(E_s(t)) = \dfrac{\int_0^{1/50} e^{-s t}E_s(t)~dt}{1-e^{-s/50}}=\dfrac{\dfrac{12}{s}(1 - e^{-s/100})}{1-e^{-s/50}} = \dfrac{12}{s(1+e^{-s/100})}$$
For the second part, we need the Laplace Transform of the second order differential equation:
$\mathscr{L}\left( \dfrac{d^2v}{dt^2} + \alpha \dfrac{dv}{dt} + \omega_0^2~v = \omega_0^2~ E_s\right)$, with $\alpha = \dfrac{R}{L}, \omega_0^2 = \dfrac{1}{LC}$, yielding:
$$(s^2~v(s) - s~v(0)-v'(0)) + \alpha (s~v(s)-v(0)) + \omega_0^2~v(s) = \dfrac{12~\omega_0^2}{s(1+e^{-s/100})}$$
Solving for $v(s)$ yields:
$$v(s) = \dfrac{1}{s^2 + \alpha~s + \omega_0^2}\left(\dfrac{12~\omega_0^2}{s(1+e^{-s/100})} + s~v(0) + v'(0) + \alpha~v(0)\right)$$
Substitute all of your initial conditions, resistor, inductor and capacitor component values and then do partial fractions on the right-hand-side and then find:
$$v(t) = \mathscr{L^{-1}}~(v(s)) ~~\mbox{Volts}$$
Note: the result above matches your posted result because $v'(0) = v(0) = 0, V_m = 12, T = \dfrac{1}{50}$.
Just replace the component values and find the inverse Laplace Transform and you are done.