I came across a couple occurrences of this notation in my notes. Here’s one example:
Ex. The quotient space X/~ where $X=\lbrack 0,1 \rbrack$ with the Euclidean topology, and $\sim$ the equivalence relation generated by $0\sim 1$.
What does that mean? How do I determine the other pairs in that relation?
In this case, it means $a\sim b$ iff $a=b$ or $a,b\in\{0,1\}.$ That is, it is the smallest equivalence relationship on $[0,1]$ such that $0\sim 1.$
You'll see this as a short form of defining equivalence relations a lot, such as the definition of the Möbius strips as $X/~$ where $X=[0,1]\times[0,1]$ where $(x,0)\sim(1-x,1)$ for all $x\in[0,1].$