What is the significance of the largest/ smallest eigen values?

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I want to know what is the significance or importance of the largest and smallest eigenvalue in graph analysis (social network).

I understood how eigenvectors helps to find the centrality of the nodes in graph. But I'm wondering how the smallest and largest eigenvalues are useful in graph analysis.

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Eigenvalues and eigenvectors of Laplacian of a graph can give a complete description of graph topology (it is the same as knowing the weight matrix.).

For instance, $0$ eigenvalues show the number of isolated subgraphs and eigenvectors of these $0$ eigenvalues are constant through the subgraphs.

As eigenvalues increase corresponding eigenvectors (localized to different subgraphs) start to have more high-frequency components.

In fact, Graph Signal Processing people do use eigenvectors as a Graph Fourier Transform basis.

In short, eigenvectors corresponding to small eigenvalues tend to include low-frequency components of the graph topology while large eigenvalues tend to correspond to fast-changing components of the topology.