I'm interested in knowing some values of the zeta function at infinite inputs. If we accept that $$\zeta(\infty) = 1$$ (as shown here in WolframAlpha) then, is it possible to evaluate the zeta function at a divergent series? To be specific, let's take the harmonic series.
Question. What is the value of $$\zeta \left( \sum_{n=1}^{\infty}\frac{1}{n} \right)$$ and is it equal to $\zeta(\infty)$?
There is nothing fancy going on here. If $$H_n = \sum_{k=1}^n \frac{1}{k}$$ then $\displaystyle \lim_{n \to \infty} H_n = \infty$ and since $\zeta(s) \to 1$ as $s$ goes to infinity along the real line, we conclude $$\lim_{n \to \infty} \zeta(H_n) = 1.$$ I believe this is the most obvious interpretation of your symbols.
Given the consternation in the comments, I feel I need to mention the following:
Now we are in a position for a satisfactory resolution of your problem. First, we interpret $$\sum_{n=1}^\infty \frac{1}{n} = +\infty \in \overline {\mathbb{R}}.$$ In my answer above, I implicitly considered $\zeta$ as a function of a real variable only, because this does possess a continuous extension to $(1, \infty) \cup \{+\infty\}$. We can evaluate $\zeta(+\infty)$ by taking the limit of $\zeta$ evaluated at the partial sums $H_n$, as I did above, and under this interpretation, $$\zeta \left( \sum_{n=1}^\infty \frac{1}{n} \right) = 1.$$
However, if we are to consider $\zeta$ truly for what it is—a function of a complex variable—then we should interpret the input accordingly: either as a complex number, $$\iota^*\left(\sum_{n=1}^\infty \frac{1}{n}\right) = \iota^*(+\infty) = \infty \in \overline{\mathbb{C}},$$ or as the sum of a series of complex numbers, $$\sum_{n=1}^\infty \frac{1}{n} = \infty \in \overline{\mathbb{C}}.$$ In either case, $$\zeta \left( \sum_{n=1}^\infty \frac{1}{n} \right) \text{ does not exist.}$$
In conclusion, whether or not we have the "identity" $$\zeta \left(\sum_{n=1}^\infty \frac{1}{n} \right) = \zeta(\infty)$$ essentially depends on your interpretation of $\infty$.
And finally, the answer to your more general question "is it possible to evaluate $\zeta$ at a divergent series" is "it depends on the interpretation of the series".