There are many statements that seem to be needless of a proof since they are ‘evident’ mainly because of our intuition. But some of them have proofs. For example, in C. Adams’ Introduction to topology, the Jordan Curve Theorem has a 3-page proof but the same book says, “clearly $\mathbb{R}^n$ is path connected, as is every open ball and every closed ball in $\mathbb{R}^n$" (i.e., no need to prove).
Please note that the mentioned two statements above are just examples to explain what I mean by the main question: How trivial is something trivial?
Not directly an answer, but too long to be a comment:
Your example actually isn't very good. The book says:
This is truly a trivial statement, since every open ball in $\mathbb R^n$ is convex, and thus path connected.
The Jordan curve theorem, on the other hand, claims:
It's quite clear that this theorem is not equivalent to just saying "every open ball in $\mathbb R^n$ is path connected". In fact, this is a much stronger claim!
That said, of course there are simple statements that have never been proven. For example, the famous Goldbach conjecture is a simple example of a very simple statement that has not yet been proven: