I'm interested in the set of twice-differentiable functions $f$ such that $\exp(f(x))$ is concave for $x \in [0,1]$. This is equivalent to asking for the set of functions $f$ such that $$ \left(\frac{df}{dx}(x)\right)^2 + \frac{d^2 f}{dx^2}(x) < 0 $$ for every $x \in [0,1]$. The reasoning for this equivalence is below. I'm purposefully avoiding a non-strict inequality to avoid the trivial solution $f(x) = c$ for some constant $c \in \mathbb R$. If the entire set can’t be characterized, I would be satisfied with a single example of $f$.
Because \begin{equation} \frac{d \exp \circ f}{dx}(x) = \exp(f(x)) \cdot \frac{df}{dx}(x) \end{equation} and so \begin{align} \frac{d^2 \exp \circ f}{dx^2}(x) &= \exp(f(x)) \cdot \frac{df}{dx}(x) \cdot \frac{df}{dx}(x) + \exp(f(x)) \cdot \frac{d^2f}{dx^2}(x) \\ &= \exp(f(x)) \cdot \left[\left(\frac{df}{dx}(x)\right)^2 + \frac{d^2f}{dx^2}(x)\right] \end{align} Because $\exp(f(x)) \geq 0$ for every $x \in [0,1]$, then we want to determine the functions $f$ such that $$ \left(\frac{df}{dx}(x)\right)^2 + \frac{d^2f}{dx^2}(x) < 0 $$ for every $x \in [0,1]$.
In general, if $u:[0, 1]\to (-\infty, 0)$ is a continuous function, the function $f$ that fullfils $$(\exp(f(t)))''=u(t)$$ is concave. We know that such an ODE has a solution, for each $u$, and solving it gives us $$f(x)=\log\left(k_2+k_1x+\int_{0}^{x}\int_{0}^{y}u(t)dt\right)$$
You can just plug in your favourite negative function $u$ and you have many examples :)