What is the criteria for the Good approximation ?
e.g. we can approxiamte $\sin(x)$ to $x$ for $x<0.16 rad $ why 0.16 ? why not 0.23
enother e.g. $\tanh(x/2s)=x$ for $x<s$
and so on .. how to determaine the bounds , finding the max possible value for Good approximation , in other words : When to consider a Good Approxiamtion ?
Well, the criterion is for the inequality you want to be true... for instance, you known that $\sin x \operatorname*{\sim}_{x\to 0} x$ — and even more, $\sin x = x - \frac{x^3}{6} + o(x^4)$. This clearly means that on some neighborhood of zero, $[-u,u]$, you have $\sin x \in [x - \epsilon, x+\epsilon]$ for any $\epsilon>0$ of your choice (for instance). How to find a "good" $u$?
The most direct way is trying to solve the inequality by using all the tricks (convexity, etc) you have; or, if there is no elegant and quick way, to study for instance the function $\phi\colon x \to \sin x - x $ (and see when it is bounded by $\epsilon$) with all the tools of calculus.
You can also look for a mutiplicative approximation of the form $\sin x \in [(1 - \epsilon)x, (1+\epsilon)x]$. Then, considering $\psi\colon x \to \frac{\sin x}{x} $ and seeing when it's bounded by $(1\pm \epsilon)$ becomes the "generic, brute-force" approach.