How do we get the usually used form of $<$ (i.e. $\dots-3<-2<-1<0<1<2<3\dots$) on the real number field, defined as the Dedekind complete totally ordered field?
Why isn't it e.g. $\dots-3<-2<1<2<0<-1<4<5\dots$? $0$ is defined as the additive identity of $\mathbb{R}$ and $1$ as this set's multiplicative identity. I'm especially curious about why the additive and multiplicative identities are placed the way they are.
They aren't placed there. They were already there. Natural numbers were for counting. If you want to count backwards, you would need to extend to integers. If you want to count in halves or thirds and so on, you would need to extend to rationals. Finally, if you have a sequence of rationals that 'converge' (such as Cauchy sequence), you need real numbers otherwise the 'limits' would not exist. So where $0$ and $1$ end up in the real line is simply where they started off in the natural number sequence. They didn't choose to have particular locations in the real line, nor did we. All those intervening rationals and reals just 'happen' to fill the 'gap' in between $0$ and $1$.