As far as I know, the matrix: $$M = \begin{pmatrix}1 & 0 & i\sqrt{3} \\ 0 & 2 & 0 \\ -i\sqrt{3} & 0 & 3 \end{pmatrix} $$
Is hermitian with eigenvalues: $\lambda_1 = 0, \lambda_2 = 2, \lambda_3 = 4$.
And corresponding eigenvectors: $V_{\lambda_1 = 0} = \begin{pmatrix}-i\sqrt{3} \\ 0 \\ 1\end{pmatrix} $, $V_{\lambda_2 = 2} = \begin{pmatrix}0\\ 1 \\ 0\end{pmatrix} $, $V_{\lambda_3 = 4} = \begin{pmatrix}\dfrac{i}{\sqrt{3}}\\ 0 \\ 1\end{pmatrix} $
Since these are eigenvectors of distinct eigenvalues they should be orthogonal but the first and third are not orthogonal.
Why is this?
They are orthogonal. \begin{align}V_0^HV_2&=0\\ V_2^HV_4&=0\\ V_0^HV_4&=\begin{pmatrix}i\sqrt3&0&1\end{pmatrix}\cdot\begin{pmatrix}\frac i{\sqrt3}\\ 0\\ 1\end{pmatrix}=0\end{align}