In 2.2 of this paper, the argument runs through the fact that the 3-type of $S^2$ cannot be delooped. Why not?
I understand that this is probably a fairly basic fact of homotopy theory (hence neither that paper nor this paper, which it cites, providing an explanation or source for the fact). All I know of homotopy stems from studying higher categories & groupoids, so I'm weak on the basics. Unfortunately, my google-fu has failed me, and I haven't been able to find a source that discusses why the 3-type of the 2-sphere cannot be delooped. I'd appreciate a pointer to an appropriate text, and I'd appreciate a quick explanation of why this should be so even more.
Let $X$ denote the $3$-type of $S^2$. The only nontrivial homotopy groups of $X$ are $\pi_2(X)\cong\mathbb{Z}$ and $\pi_3(X)\cong\mathbb{Z}$. Suppose $X$ could be delooped, so there is a connected space $Y$ such that $X\simeq \Omega Y$. The only nontrivial homotopy groups of $Y$ would be $\pi_3(Y)\cong\mathbb{Z}$ and $\pi_4(Y)\cong\mathbb{Z}$.
Now a homotopy type with only two nontrivial homotopy groups $\pi_m(X)\cong A$ and $\pi_n(X)\cong B$ ($n>m$) is classified by its $k$-invariant, a cohomology class in $H^{n+1}(K(A,m);B)$. Explicitly, such a cohomology class corresponds to a map $K(A,m)\to K(B,n+1)$ (up to homotopy) and then you take the homotopy fiber of this map to get your space.
So, our delooping $Y$ would be classified by a class in $H^5(K(\mathbb{Z},3);\mathbb{Z})$. Now it happens that $H^5(K(\mathbb{Z},3);\mathbb{Z})$ is trivial (you can compute the cohomology of $K(\mathbb{Z},3)$ from the cohomology of $K(\mathbb{Z},2)=\mathbb{CP}^\infty$ using the Serre spectral sequence, for instance), so the $k$-invariant of $Y$ is trivial, so actually $Y\simeq K(\mathbb{Z},3)\times K(\mathbb{Z},4)$. It then follows that $X\simeq K(\mathbb{Z},2)\times K(\mathbb{Z},3)$. But this is false: it would imply, for instance, that $H_3(X;\mathbb{Z})$ is nontrivial (since $H_3(K(\mathbb{Z},3);\mathbb{Z})\cong\mathbb{Z}$), but $H_3(X;\mathbb{Z})\cong H_3(S^2;\mathbb{Z})$ is trivial.