I'm more familiar with the notation $a \equiv b \pmod c$, but I think this is equivalent to $a \bmod c = b \bmod c $, which makes it clear that we should put a $=$ instead of $\equiv$.
What's the reason for the change of sign? If it's to emphasize that modular equivalence is a congruence relation, why don't we use the $\equiv$ sign in both notations?
It depends on how you define your notation. The standard definition of congruence is $a \equiv b \pmod c$ if and only if $c \mid (b-a)$. The standalone expression $b \pmod c$ is undefined, hence not equal to anything.
On the other hand, some people like to write "$b \bmod c$" to stand for the least nonnegative number $d$ that satisfies $d \equiv b \pmod c$. If you adopt this notation then it is true that $a \equiv b \pmod c$ if and only if $(a \bmod c) = (b \bmod c)$.