Let $V$ a $K-$vector space and $V^*$ it's dual. What is the motivation of using the notation $\left<\varphi,x\right>$ for $\varphi(x)$ ? Is it a consequence of the fact that \begin{align*} \left<\cdot ,\cdot \right>: V^*\times V&\longrightarrow K\\ (\varphi,x)&\longmapsto \left<\varphi,x\right>=:\varphi(x) \end{align*}
would be a scalar product ? But it looks strange since a scalar product must take element form $V\times V$ or $V^*\times V^*$, but not of the form $V^*\times V$.
When $V $ is a Hilbert space (a very common situation, for instance in physics), you have $V^*=V $, so it is an actual inner product.