Let $\rho$ be an Hermitian matrix with unit trace (this is the context I've found this result stated in, but I don't know if these restrictions are necessary for the result). Suppose $p_i\ge0$ with $\sum_i p_i=1$, and let $U_i$ be unitaries. Consider $$\rho'= \sum_i p_i \, U_i \rho U_i^\dagger.$$ Then $\rho'\preceq \rho$, by which I mean that the vector of eigenvalues of $\rho'$ is majorized by that of $\rho$. I think this is shown in the reference "A. Uhlmann, Wiss. Z. Karl-Marx-Univ. Leipzig 20, 633 (1971)" but I could not find an English version of it.
For $p_i=\delta_{i0}$ the result is clear, as $U\rho U^\dagger$ has the same eigenvalues of $\rho$. How do you prove the general case?
This is a consequence of the following result: for a size $n$ Hermitian matrix $A$, let $$ \lambda_1(A) \geq \lambda_2(A) \geq\cdots \geq \lambda_n(A) $$ denote the eigenvalues of $A$. For symmetric matrices $A_1,\dots, A_m$, we have $$ \sum_{j=1}^k \lambda_j\left(\sum_{p=1}^m A_p \right) \leq \sum_{j=1}^k \sum_{p=1}^m \lambda_j(A_p). $$ This in turn can be seen as a consequence of the fact that $$ \sum_{j=1}^k \lambda_j(A) = \max_{U \in \Bbb C^{n\times k}, U^\dagger U = I} \operatorname{tr}(U^\dagger A U). $$
Explanation of the inequality: note that \begin{align} \sum_{j=1}^k \lambda_j\left(\sum_{p=1}^m A_p \right) &= \max\left\{\operatorname{tr}\left[U\left(\sum_{p=1}^m A_p \right)U^\dagger \right]: U \in \Bbb C^{n\times k}, U^\dagger U = I\right\} \\ & = \max\left\{\sum_{p=1}^m \operatorname{tr}\left[UA_pU^\dagger\right] : U \in \Bbb C^{n\times k}, U^\dagger U = I\right\} \\ & \leq \max\left\{\sum_{p=1}^m \operatorname{tr}\left[U_pA_pU_p^\dagger\right] : U_p \in \Bbb C^{n\times k}, U_p^\dagger U_p = I \text{ for } p = 1,\dots,m \right\} \end{align}