Given the identity here, to me it seems that this should be true: $$\sum_{i = 0}^{n}\binom{n+i} i\binom{2n-i}{n-i} = \binom{3n}{n}$$
But it seems that this is not the case.
It turns out that it is actually $$\sum_{i = 0}^{n}\binom{n+i} i\binom{2n-i-1}{n-i} = \binom{3n}{n}$$for $n\ge1$.
Why is this the case? Shouldn't the above technically follow Vandermonde's identity?
Here we have Chu-Vandermonde's identity in disguise. The crucial point is that we have the bound variable $i$ not only as lower index, but also as upper index of the binomial coeffcient. Nevertheless we can transform the binomial coefficient using the binomial identity \begin{align*} \binom{p+q-1}{q}=(-1)^q\binom{-p}{q}\tag{1} \end{align*} and then we can apply Chu-Vandermonde's identity.
Comment:
In (2) we apply the binomial identity (1) twice.
In (3) we are ready to apply the Chu-Vandermonde identity.
In (4) we apply (1) again.