I have just learned that every relation which is both left-total and right-unique is called map or function.
Why is $f: \mathbb{R} \rightarrow \mathbb{R}, x \mapsto {1 \over x}$ or as relation $G = \{(x,y) \in \mathbb{R} \times \mathbb{R} \mid y = {1 \over x}\}$ a function?
To be left-total, $\forall x \in \mathbb{R} \exists y \in \mathbb{R}: (x,y) \in G$ must be true. But that is not true for $x=0$, since ${1 \over 0} \notin \mathbb{R}$.
Is that special case simply ignored since it is not "allowed" to divide by zero or am I missing something?
There is no function $f: \mathbb{R} \to \mathbb{R}$ defined by $x \mapsto \frac{1}{x}$, for the reason you state: it doesn't assign a value to the input $0$.
The function $x \mapsto \frac{1}{x}$ is usually given with domain $\mathbb{R} \setminus \{0\}$.