A. It is possible to find distinct $z_1,z_2,z_3\in \mathbb C$ such that $|z_1-z_2|=|z_1-z_3|=|z_2-z_3|$.
Answer: True
B. It is possible to find distinct $z_1,z_2,z_3, z_4\in \mathbb C$ such that $|z_1- z_2|=|z_1-z_3|=|z_2-z_3|=|z_1-z_4|=|z_2-z_4|=|z_3-z_4|$.
Answer: False
I don't understand why the second one is false. Can anyone help me out?

You can think about $\mathbb{C}$ as a two dimensional plane (that is, like $\mathbb{R}^2$). Each complex number defines a point in the plane, and given two complex numbers $z$ and $w$, $|z - w|$ is the distance between them, or the length of the line segment which joins them.
For three complex numbers $z_1$, $z_2$, $z_3$, the condition $|z_1 - z_2| = |z_1 - z_3| = |z_2 - z_3|$ implies that the three points are the vertices of an equilateral triangle. So if you draw an equilateral triangle in the complex plane, and label the vertices $z_1$, $z_2$ and $z_3$, you will have three complex numbers which satisfy the required condition. In your comment you asked whether $z_1 = z_2 = z_3$. This is not the case as the question asked for the numbers to be distinct.
For four complex numbers $z_1$, $z_2$, $z_3$, $z_4$, the condition $$|z_1 - z_2| = |z_2 - z_3| = |z_3 - z_4| = |z_1 - z_4|$$ implies that the four points are the vertices of a rhombus (labelled cyclically). However, the question asks about four complex numbers which satisfy the stronger condition $$|z_1 - z_2| = |z_2 - z_3| = |z_3 - z_4| = |z_1 - z_4| = |z_1 - z_3| = |z_2 - z_4|.$$ If four such complex numbers did exist, they would have to be the vertices of a rhombus labelled cyclically, but note that $|z_1 - z_3|$ and $|z_2 - z_4|$ are the lengths of the diagonals of the rhombus. So $z_1$, $z_2$, $z_3$, $z_4$ would have to be the vertices of a rhombus which had equal side and diagonal lengths, but no such rhombus exists (the diagonal length is always greater than the side length).