When calculating the Euler Characteristic of any regular polyhedron the value is 2. Since a sphere is homoeomorphic to all regular polyhedrons, the sphere ought to have a Euler Characteristic of 2 as well.
So:
$V-E+F=2$
holds true
A sphere obviously do not have vertices nor edges, which ought to mean they have 2 faces, which i assume are the inside and outside.
If that is the case, why dont you count the inside and outside as two seperate faces on any of the other regular polyhedrons? A tetrahedron for example only has 4 faces.
If not, then where is the other face.
For any triangulation of the sphere, it is true that $V-E+F=2$, where $V$ is the number of vertices in the triangulation, $E$ the number of edges in the triangulation and $F$ the number of faces in the triangulation. For example, consider the triangulation below:
There are $6$ vertices, $12$ edges and $8$ faces, so $V-E+F=6-12+8=2$.
There are also more complicated definitions of the Euler Characteristic in terms of homology or number of cells in each dimension in a CW complex. It can be defined as $$\chi(X)=\sum(-1)^n\mathrm{rank}(H_n(X))\,.$$