Let remainder $r$ be defined as $$ r = n - pq $$ where $n \in \mathbb{N}$ is the dividend , $q \in \mathbb{R}$ is the divisor, and $p = \mathrm{floor}(n/q)$.
I calculated the remainders by dividing by $\pi$ for $1,2,\dots,100000$, then I got the reminders seem to follow a uniform distribution on $[0,\pi)$.
When the divisor is rational, it's obvious that the remainder is limited to some certain values.
When it comes to a irrational divisor, it makes intuitive sense to me that the remainders can have any values on $[0,q)$, and follow a uniform distribution. However, I have no idea how to prove this.
EDIT: Added histogram.

Dividing your formula by $q=\pi$ gives $$ n \cdot \frac{1}{\pi} = p + \frac{r}{\pi} , $$ so $p$ is the integer part, and $\frac{r}{\pi}$ is the fractional part, of $n \cdot \frac{1}{\pi}$. As $n$ runs through the integers, this fractional part $\frac{r}{\pi}$ is uniformly distributed on $[0,1)$ by Weyl's equidistribution theorem, since $\frac{1}{\pi}$ is irrational. Hence $r$ is uniformly distributed on $[0,\pi)$.