Example: Let's presume one was attempting to isolate m below:
A common mistake would be: $k^2 = m^2 + n^2 \to k = m +n$
Even though: $k^2 = m^2 + n^2 \to k \neq m +n$
If you apply a square root to both sides of the equation, you will have an inequality.
Why is this true?
If you put the question in a broader context you may understand it better.
Suppose $f$ is some function you can apply to numbers. It might be squaring, or square-rooting, or inverting, or raising to some other power, or taking logarithms or $\sin$ or $\cos$ or just adding 15. In none of these cases is $f(x+y)$ the same as $f(x) + f(y)$ (you should check). In general, you would not expect that coincidence.
The special case in which it is true is the function "multiply by a fixed quantity". That's the distributive law:
$$ c \times (x + y ) = c \times x + c \times y . $$
Many of the most common errors students make in algebra or precalculus come from thinking that those other functions behave this way too.
Edit: Just in case you missed @Rahul 's comment: What we need here is a cure for the “law of universal linearity”: Pedagogy: How to cure students of the "law of universal linearity"?