With division, you can have a remainder (such as $5/2=2$ remainder $1$). Now my six year old son has asked me "Why is there no remainder with multiplication"? The obvious answer is "because it wouldn't make sense" or just "because". Somewhat I have the feeling that prime numbers are a bit like the remainders as you can never reach them with multiplication.
Is there a good answer to the question? (Other than the trivial ones?)
Additional comments after many answers are written:
I am really grateful for all the answers! It's a shame that I can't accept more than one. (A side note: I really hesitated to ask this question as I felt that this is a dumb question, I almost deleted it after I posted it. Now that I have received so many interesting points of view, I will try hard to find good examples when the next topic comes along to make him get a mathematical sense.)
What I lacked (or the math teacher/book) is answers like you gave before multiplication and division were introduced (as written in a comment).
Division with remainder is part of his math book (2nd grade, but a bit optional). So asking this question didn't surprise me that much.
I believe when he was taught the integer numbers, all examples (from me and perhaps the teacher) in the beginning were like "4 apples plus 5 apples equals ...". Then the math book introduces subtraction (still explainable with apples). With multiplication and division, the problems lost concrete examples and the "pure math" gets more dominant. And perhaps there was a bit too much focus on symmetry (plus and minus and multiply and divide are opposite), which is true, but not (obviously, that's where the question arose) completely true.


I'll try it the 'Lego way' (sorry for the publicity)
When we multiply two positive numbers we get 'perfect' rectangles ($48=6\times 8$) :
$\qquad$
When we add some small squares at the bottom of the rectangle and divide by the width we get a remainder except if we added the whole width again ($52=6\times 8+4$) :
$\qquad$