One can see by brute force that $x^3+2x+2$ has no roots in GF(3). So it is irreducible and hence the minimal polynomial of $\alpha$.
My question is what is $\alpha$, how can I think about it? I determined that $GF(3)(\alpha) \cong GF(3^3)=GF(27)$. I then wrote a script to check $1,2,3,\dots,26$ to see if they are a root $\mod 3$ and $\mod 27$, and none of those are... Do I have a misconception about $\alpha$?
You can think of this field by analogy with how you first thought of the complex numbers: as the real numbers with an extra element $i$ such that $i^2+1 = 0$.
In this case you start with $GF(3)$ and "add" an extra element $\alpha$ that satisfies the given polynomial. Then every element is a combination $$ x + y\alpha + z\alpha^2 . $$
The defining equation tells you how to express $\alpha^3$ this way, by analogy with $i^2 = -1$.