I would first like to say that I completely understand why and how this works. In the set $\{1, 2, 3, 4, 5, 6, 7, 8, 9, 10\}$, there are 5 even numbers, and 5 odd numbers. Assuming we choose our first 5 numbers with the same parity, all of their sums are even. This is because $even + even = even$ and $odd + odd = even$
However, when we pick our sixth and last number, this number will have the opposite parity, meaning we have at least one odd sum, since $even + odd = odd$.
However, I am having trouble clearly defining what the pigeons and pigeonholes are. At first, I thought it was
Pigeons: 6 integers, at least one will be opposite parity
Pigeonholes: 5 ???s
But after some thought, I think it is
Pigeons: 1 remaining opposite-parity integer
Pigeonholes: 0 acceptable spots for an opposite parity integer in order to maintain even sums
However, this just seems wrong and kind of unintuitive. I would appreciate any help in explicitly defining the pigeons and pigeonholes.
Welcome to MSE!
You have the exact right idea!
Why not let your holes be $\{1,2\}$, $\{3,4\}$, $\{5,6\}$, $\{7,8\}$, and $\{9,10\}$?
Then you're guaranteed $2$ pigeons in the same hole, but the sum of two consecutive numbers is odd.
I hope this helps ^_^