What is the probability that only $1$ out of the first $4$ you picked are black?
So it is clear that we have picked $4$ balls. Our $4$ spots can be as follows:
$\mathrm{BWWW}$
$\mathrm{WBWW}$
$\mathrm{WWBW}$
$\mathrm{WWWB}$
$4$ ways to orient this.
There are $6$ W balls, from those we must pick $3$.
There are $4$ B balls, from those we must pick $1$.
Thus:
$$\frac{\displaystyle\binom{6}{3}\binom{4}{1}}{\displaystyle\binom{10}{4}}$$
Is this correct?
Your answer is correct and is a good example of use of the hypergeometric distribution.