In the book of Topology by Munkres, at page 130, it is given that
But I do not understand how can he concludes the converse result with the proof that he provided. I mean shouldn't we have chosen an arbitrary open set $U$ around $x$ and show that $\exists N $ s.t $\forall n \geq N$ $$x_n \in U \quad ?$$

No. The converse is this:
So, now he is assuming that $f$ maps convergent sequences into convergent sequences. And he wants to prove that $f$ is continuous, which he does using the fact that the continuity of $f$ is equivalent to the assertion that, if $A\subset X$, then $f\bigl(\overline A\bigr)\subset\overline{f(A)}$.