By way of introduction, a standard normal random variable $X$ has MFG $E[\exp(tX)]=\exp(t^2/2)$. A symmetric subgaussian random variable $Y$ with unit proxy variance is one such that $P(Y< -t) = P(Y>t)$, and $P(|Y|>t)\le 2 \exp(-t^2/2)$ or, equivalently, $E[\exp(tY)]\le\exp(t^2/2)$. The conjecture is the following: let $f:\mathbb R\rightarrow \mathbb R$ be an even function, so that $f(X), f(Y)$ are also symmetrically distributed. The conjecture is that
$$E[e^{tf(Y)}]\le E[e^{tf(X)}]$$
It is true for the very special case where $f$ is the identity.
N.B.: I edited the question and required symmetry of $Y$ and $f$.
Symmetry does not seem to be the right concept here.
For example, sample $Y$ uniformly in $\{-1, +1\}$ -- the typical example of an $O(1)$-subgaussian random variable -- and define $f(x)=1$ if $x=1$, $f(x)=-1$ if $x=-1$ and $f(x)=0$ elsewhere. Then $\mathop E e^{tf(Y)}=(e^t+e^{-t})/2$, but $\mathop E e^{tf(X)}=1$ since $f(X)=0$ almost surely. Your inequality is violated if you pick $t$ large enough.
Of course, the issue is not with $f$ being discontinuous, one could always approximate it by some continuous function and get the same result.