It is trivial to satisfy just one of them. In 2D for example ($r = \sqrt{x^2 + y^2}$ below), $\nabla\cdot(x,-y) = 0$. However, $\Vert v \Vert = r$, so only the divergence condition is satisfied. On the other hand for $(x/r, y/r)$, we have $\Vert v \Vert = 1$ but $\nabla\cdot v=1/r$ instead of 0.
Note that the first one is a differential constraint, whereas the second one is only an algebraic constraint. Is there a standard name for this kind of problem that involves a mixture of both algebraic and differential operations?
Edit: A uniform unit vector field is excluded because it's trivial.
Edit: Solution in 2D
Thanks to the paper @LuisFerreira pointed to me, I can construct a 2D field that satisfies the requirement, except at some singular points. The proof in the paper is beyond me so unfortunately I can not explain why such singularity exists.
First: recognize that $v = \nabla^\perp \psi$, where $\psi$ is the stream function and the operation gives a 2D vector field $(\psi_y, -\psi_x)$. Then the divergence condition is satisfied automatically
Second: the norm constraint is $\Vert v \Vert = \Vert \nabla^\perp\psi \Vert = \Vert \nabla \psi \Vert = 1$. The 2nd equality is clear if you express them in components. $\Vert \nabla \psi \Vert = 1$ is the Eikonal equation, a classical solution of which is the distance field.
Example, the distance field to the origin is $\psi(x,y)=r=\sqrt{x^2+y^2}$, so $$ v = \nabla^\perp \psi = \left( \frac{y}{\sqrt{x^2+y^2}}, -\frac{x}{\sqrt{x^2+y^2}} \right) $$
A plot
$v$ is divergence free and has unit length, but it's singular at the origin.
Comment In 3D we don't have scalar stream function so the problem can be quite different/difficult (we do have vector potential, which itself is a vector instead of scalar field, so I don't think it will help).
Edit Another 2D example based on the distance field of an ellipse. This one won't permit any analytical description.


These are usually called Differential algebraic equations, which involve a mixture of differential equations and algebraic constraints. Note that these are different from algebraic differential equations, which are a whole other beast.
EDIT: It seems like you were also looking for an actual solution to this equation and I missed that, so I'll try to find some direction at least: Since $\|v\|=1$, we can write $v(x,y)=(v_1(x,y),v_2(x,y))$ as $(cos(\theta(x,y)), sin(\theta(x,y)))$. Applying divergence to this expression, we arrive at $cos(\theta)\frac{\partial \theta}{\partial y}-sin(\theta)\frac{\partial \theta}{\partial x}=0$, which isn't a very nice PDE to deal with.
EDIT: This paper appears to have some interesting results, but might be too technical for what you're looking for.