Suppose $F : Preord \to Cat$ is the inclusion functor. Suppose that $G : Cat \to Preord$ is the functor which maps each category $C$ to its associated preorder (each object is an element and $X \leq Y$ iff there is a morphism from $X$ to $Y$ in $C$).
To show that $G$ is the left adjoint to $F$, I'm trying to come up with an isomorphism $$\phi : hom(GC, D) \to hom(C, FD)$$ but I can't seem to make sense of what it should look like.
Warning: I'm not exhibiting the mapping $\phi$ per se, I'm just giving another way to prove that $G$ is the left adjoint.
Here is a useful lemma:
So in your case, given a small category $c$, let us write $a_c : c \to \bar c$ for the functor that collapses every parallel arrows, so that $\bar c$ is the preorder associated to $c$ viewed as a category (that is $F(G(c))$ in your notation). You now have to check that: